You will want to take a look at the examples in LabVIEW that deal with pulse train generation. As long as you have the driver and LabVIEW installed correctly, the examples should be located in the Example Finder under Hardware Input and Output >> DAQmx >> Generate Digital Pulses. You will want to select the example that fits your most desired operation (i.e. triggering, continuous, fininte, train, or pulse).
These examples are written for a single counter output. If you want to take advantage of using multiple counters, you will have to change the examples to do so. Use your good programming skills to setup both counters to begin on the same digital trigger, and then assign one of them an initial delay, as is possible by setting the input parameter on the CO Pul
se Freq VI.
The examples also come with excellent instructions. If you open your Context Help Window and hover your mouse over the VI's icon in the top-right corner, the Context Help Window will be populated with the directions.
Jared A