Hey Jon,
I'm unsure if the SR400 is able to trigger externally, but if in the manual for the SR400, you're able to find the command for it, you should be able to easily implement it. If it's GPIB communication, just open labVIEW, and go to Help->Find Examples->and Search for GPIB, and you should find a nice example called "labVIEW<->GPIB.vi". If it's serial communicaiton, just search "Serial" and you should be able to find a nice example called "Basic Serial Write and Read.vi". Just copy the triggering command if it's found in the manual into the write field, and you should have no problem implementing it. I like these two examples a lot, because they're easy to build from.
Regards,
Nick D.