Hi Mike,
Have a look in the DAQmx examples for how to generate a clock source. Go to Help » Find Examples in LabVIEW and browse to Hardware Input and Output » DAQmx » Gen Dig Pulse Train-Continuous.vi. This will output a square wave of settings you specify to the default PFI line for your hardware.
Once you are running this, you can then use another example, such as Hardware Input and Output » DAQmx » Cont Write Dig Port-Ext Clk to output digital signals using the square wave as the timebase.
Finally, you can route the clock to other pins using the DAQmx routing VIs - go to the functions palette in LabVIEW then to Measurement I/O » DAQmx » DAQmx Advanced » DAQmx Signal Routing. Have a look at the help for these functions that let you route your clock source around.
Hope that helps!
Tom
Applications Engineering, NI UK