Hi rajen-
It sounds like you're trying to extend PWM capabilities to the digital outputs of your E Series card. In order to use PWM you need precisely timed hardware operations so that you can accurately time the widths and durations of your pulses.
This functionality will not be easy to accomplish with your card because it does not feature hardware-timed digital output capabilities. If you would like to use digital outputs for precise hardware-timed digital operations you will need to upgrade to an M Series card with correlated digital I/O.
I hope this helps!
Thanks-
Tom W
National Instruments