Jeff,
You're probably wondering why there are separate grounds if you can connect to both. Usually, Digital IO signal interaction isn't affected by EM. As long as the signal gets from point a to point b, in the digital world you're fine. But analog is a whole different beast which can be affect by EM or noise. Analog signals are influenced by what's going on around them. So usually you keep the analog portion of a PCB away from the Digital side. THE EM from the digital ground could affect the analog portion of a circuit. But NI is really good about protecting your signals so you're probably fine. If you get junk data, separate your grounds to make sure you're not picking up radiation from the digital side.
Hope this helps