Appologies, its a PCI-6733 not 7633.
I have also solved my initial problem by an alternative approach but also beleive I know how to solve the general digital out issue.
The solution I found was to use a counter timer to generate a frequency output on ctr0out with a given duty cycle, the waveform I wanted was periodic. This I have then used to clock out an analogue signal, solving that sync problem. Finally I have another counter timer, driven from the ctr0 again, which divides the clock down further to generate another digital pulse but at a lower frequence.
The original problem I thin can be solved by feeding a standard digital out channel with a valid clock. I did not realise that the digital outputs did not have an associated default clock, as do the analogue ports.
Thanks.