Mike,
If you place a router inside your enclosure, you can have one external IP address which is presented to the outside world as the box IP address and have three internal IP addresses (one for the cFP and two for the ENET-232s).
The inter-module communication bus on FP/cFP was designed for single point style readings rather than buffered acquistion type readings. Thus, I personally doubt that NI will bother with making a FP/cFP Serial module especially as the ENET-232 and ENET-485 boxes are already supported natively through LabVIEW.
Regards,
Aaron
LabVIEW Champion, CLA, CPI