Hello Prasad,
I think the Register Level Programming page will be helpful for you. You can refer to the Application notes to get an idea of how the TNT 4882 chip is used with other microcontrollers. It will also help to look at the Data sheet for the TNT 4882.
The TNT is compatible with any microcontroller or processor that allows you to do reads/writes. Any microcontroller
that can address an 8-bit chip should be able to use the TNT. Some microcontrollers have interrupt capability which the
TNT can use, and some do not (in which case they can use the programmed I/O feature of the TNT).
You will need to use the ESP. You will need a C based compiler for the PIC. The ESP package will help
you program the chip..but you will need to know specifics of
your PIC.
If you have any questions, please contact us via email by going to www.ni.com/ask and selecting "Email an Engineer".
Good Luck,
Kim L.
Applications Engineer
National Instruments