RS-232 can be +-12V or more depending on how the physical drivers are configured. However, if you can handle these voltages, then you can simply assert or deassert one of the modem control lines (RTS or DTR) to indicate your alarm state. If you want to use the TX line, you can set and clear the break condition. If you hook up a multimeter to one of these signals and experiment with NI-VISA in LabVIEW, you should be able to create a signal that will work in your system.
However, if you need +5/GND, you can use an RS-485 port which generates (well, in a way) signals between 0 and 5V (or 0 and 3.3V depending on the system). RS-485 is a differential signaling system, but you can just throw away one of the lines. In this case you'll use TX+, TX-, RTS+, or
RTS- depending on what you need.