Hi Liam,
Thank you for the extra info, am I right in thinking that the GPIB card you are using, the 'CEC488' is not a National Instruments card, but uses a driver which simulates an NI 488 interface?
Your problem probably lies either in you GPIB card and PC or in the formatting of the command. Does the GPIB card work with other instruments? Are you using the most up to date version of the card's and instrument's driver software? If the GPIB card isnt an NI card I cant really help as we dont support support 3rd party card drivers. I did some research into the Keithley instrument drivers that we have on our website and they appear to be supported by Keithley, have you tried contacting them?
Chrism