Do you have DAQmx installed?
I've done some analog input triggering, and some digital triggering and it worked great with my M-series card, but only after using DAQmx. Traditional DAQ (even using VIs supplied kindly from NI) had problems.
I don't know about synchronising different types of measurements at the same time (AI and AO together) but at least the rate and moment of each individual sample should be synchroniseable using a hardware-triggered AI and AO. Getting the first input / output to synchronise properly might be more tricky......
LabVIEW version? NI-DAQ version?
Shane.
Using LV 6.1 and 8.2.1 on W2k (SP4) and WXP (SP2)