From the help file for Create Listener.vi:
net address specifies on which network address to listen.
Specifying an address is useful if you have more than one network card, such as
two Ethernet cards, and want to listen only on the card with the specified
address. If you do not specify a network address, LabVIEW listens on all network
addresses.
We use multiple network cards frequently and have never had a problem.
We set up a listener on one computer with no network address specified
and then a client on another computer that specifically states to
connect to X address on Y port.
The LabVIEW client/server examples let you specify address and port. I
would give them a try and see if you can get communication working.
Rob