Hi Syegg,
The PCI-6024E is TTL compatible, which would allow you to read in TTL signals via a digital input. To read a NIM signal, you would need to use an analog input.
I assume because you are using LabVIEW 6 that you are programming with the Traditional NI-DAQ driver version 7.1 or earlier (or 7.2 if you have LabVIEW 6.1). If you don't have it installed already, you can do so here:
Traditional NI-DAQ 7.1
http://joule.ni.com/nidu/cds/view/p/id/106/lang/en
To find example programs for analog input, look in this directory on your machine:
C:\Program Files\National Instruments\LabVIEW 6.0\examples\daq\anlogin\
If you let me know a bit more about your application, I can direct you to a more specific example. What sampling frequency do you require and how many channels will you be acquiring at a time?
Regards,
John Bongaarts