I'm not really into DAQ, so I'll just make some notes about the style.
In general, it looks OK. Much better than some other code I've seen, even by experienced people.
The first thing I would suggest is that you clean it up and make everything straight and clear, even at the cost of a larger diagram. I find it preferable to scroll a bit than to have to figure out what I was trying to write. The difference made simply by having the diagram clean and the wires straight is huge.
I also place quite a lot of documentation. People may claim that you can "read" a good diagram and that it's "self documenting", but I would still much rather read a free label that tells me what the programmer (including me) intended for this piece of code to do (and why, if needed) and then verify it by looking at the code than start figuring out from the code itself (and I do this even for relatively small pieces of code).
Another point is that you have some unnecessary coercions (the wait is a U32, the divide coerces to DBL, the VI inside the case accepts SGLs). This is not necessarily a big toll, but still can be removed. In newer versions coercions are clearly shown with a gray dot, but I don't think that was available in 6.0 (maybe as an option). Try searching google for Brian Benken. He has a site with some INI settings. It might be available there.
You can try reducing your SRs by using an array to hold the data, replacing the proper element each time and passing that array through the SR (although I will leave it to you to figure out how).
Try seeing if you can change the way you rebuild the array at the end. Building inside a loop is not a good thing. Once again, this is less critical in smaller arrays, but just a matter of style for some bigger arrays.
Proper error handling is important in order to know how to pinpoint an error when it occurs, although I'm not sure if any is needed in your program.
There are probably some other things that I can't think of at the moment, but in general, if it works, that's the important thing.
To learn more about LabVIEW, I suggest you try searching this site and google for LabVIEW tutorials.
Here and
here are a couple you can start with. You can also contact your local NI office and join one of their courses.
In addition, I suggest you read
the LabVIEW style guide and the LabVIEW user manual (Help>>Search the LabVIEW Bookshelf).
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