Using a Counter/Timer board wired to AI external trigger is exactly the thing to do. You can also capture the timer signal with a Analog In or Digital In, and use the data for a reference in your spreadsheets. Your spreadsheet would be a 2D array: row 0 column 0 would be timer signal at t0, column 1 could be AI-0, column 2 is AI-1, etc. The next row can be for time t1, and so on.