Hello,
I found another discussion thread in the Developer Exchange that mentions a user having success doing Lorentzian peak fits with the Levenberg-Marquardt VI that ships with LabVIEW. Here's the URL to that discussion thread:
http://exchange.ni.com/servlet/ProcessRequest?RHIVEID=101&RNAME=ViewQuestion&HOID=5065000000080000007E020000&ECategory=LabVIEW.LabVIEW+General
Also in this thread are a few suggestions as to other places to look on the web for peak fitting routines in LabVIEW.
I hope this helps you out. Good luck with your application, and have a pleasant day.
Sincerely,
Darren Nattinger
Applications Engineer
National Instruments