I assume you mean LabVIEW 6.1.
Building an application irreversibly removes the diagram of all, and the front panel of most VIs.
To get a list of VIs and subVIs contained in the executable, rename it from *.exe to *.llb. Then use the found VI names to scavenge through the programmers old computer for matching files. Maybe you get lucky!
Can you still contact him?
Given the correct version of a properly installed runtime engine, the program should probably work as-is under W2000. Have you tried?