Since the NI-DAQ driver software is multithreaded, a multiprocessor system would have enhanced performance over a single processor system. Either way, you can have multiple handshaking digital I/O cards in a system for high speed acquisition, granted you have enough operating system resources (DMA, IRQ) for the cards.
You can find more information about this by going to the http://www.ni.com/support page and searching All Technical Resources for the keyword "multiprocessor". You will find an excellent NI Developer Zone presentation, as well as tutorials and other technical documents.
Geneva L.
Applications Engineer
National Instruments
http://www.ni.com/ask