You can use the lookout protocol drivers in Labview (it is sold as the Industrial Automation OPC Server). This has drivers that will create an OPC server that can talk to the Siemens S5 PLC. You will use data socket to commuinicate to the OPC server. You can also go to BridgeView or upgrade to Labview 6 with the DSC module. Any of those solutions will allow you to communiate with the Siemens Simatic PLC using either the AS511 protocol or the 3964-3964R protocols.