Hi M^2,
The DAQmx Export Signal.vi you have in there is routing a Reference Trigger event to the PFI9 line. I'm not sure this is what you are wanting to do.
Your application sounds like the following:
1. Acquire a analog input when a trigger condition is met. This trigger condition is a falling edge of the analog input signal.
The VI you attached should work, I made a slight change to the source of the trigger condition and removed the DAQmx Export Signal. The analog signal to be monitored should be wired to pin 20, the source is "/Dev1/APFI0". Where Dev1 is whatever name your daq card is known by to MAX.
I hope this helps! Please consider the suggestion made by falkpl as well, that would definetly cause the trigger slope to be exactly reversed.
Best regards,
MatthewW
Applications Engineer
National Instruments