You need to define the limits of integration. There's several methods out there, such as threshold above baseline or based on derivatives (or the simplest is user defined). Once you define the peak start and end, it's a simple matter to integrate the curve and get the half width. You could probably search for some HPLC or CE programs that already do this, such as this one (cheap plug for myself):
http://www.umich.edu/~rtkgroup/NetworkMI.htm
2006 Ultimate LabVIEW G-eek.