Hello @,
What version of LV do you have? LabVIEW 7.x has a "Write LabVIEW Measurement File.vi" express VI that will be the easiest way to write all of your data to a file at the same time. This VI is easy to use and includes information such as header, channel labels, and time information. If you have LV 7.x I would highly recommend this solution as an easy soluion.
thanks for contacting NI,
-Brett