You have to use the DAQmx Start Trigger.vi to synchronize the tasks. Check out the NI Example Finder and look in: Hardware Input and Output>DAQmx>Synchronization>Multi-Device. You can name the device to be the master and have the other card(s) trigger off of various conditions to allow synchronization through the PXI chassis or a RTSI cable.
LabVIEW Pro Dev & Measurement Studio Pro (VS Pro) 2019