Hi Crystal,
yes you can use Excel activeX library to create a worksheet, fill it with your data, save and print it.
In LV you can find an example:
\examples\comm\ExcelExamples.llb\Write Table to Excel.vi; this could be a good starting point.
Eventually, you can consider purchasing tha LabVIEW Report Generation Toolkit; you can create nice reports with little effort.
Good luck,
Alberto