Minimize the number of clicks (and mouse movement) the operator needs to perform. That improves test throuput, as the guy above them says (and he propably judges your equipment). So the best might be 3 Windows (Dialog style) with Cancle/Confirm and End/Again at the last one.
The operators won't take a close look (they do it day by day), so when you need their attention, use red/green color. And minimize information. On the other hand, they don't need a stylish GUI, they are happy to get the UUTs through (thats what they are payed for).
Don't care about them more, because it is their job is to use any UI. And they are good at their job (I really love them, how they accomodate to some old fashiond software I designed years ago).
And have a thinking who else is going to see the software (customers, engineers, CEOs, visitors, researchers/sientists ...). Their objectives are different.
For the Diagram, a state machine is great in that case.
One more thing about the UI: when users feel unsure, they try to close the window AND they like to have a cancle button. So have an action for both (normally the same) is a good idea.
Felix