CVI includes the ANSI C sin function. The input is in radians.
Use a loop if you want to create a array of data.
#define PI 3.14159265
//...
int numberSteps = 100;
int amplitude = 1;
int i;
double *sineWave;
sineWave = malloc (sizeof(double) * numberSteps);
for (i=0; i < numberSteps; i++)
sineWave[i] = amplitude * sin(i*2*PI/numberSteps);
The CVI Advanced Analysis Library also includes the following function which does some of the work for you.
int SineWave (int n, double amp, double f, double *phase, double x[]);