The ValueMotion boards only support simple linear point to point vector moves so there is no way to generate any curved profiles with this board type.
The boards of the 7344 series (FlexMotion) support various types of motion modes like circualar interpolation or contouring mode where you can download arrays of position data to the board and the board interpolates the move through these points.
You can find more information about the 7344 board following this link:
http://sine.ni.com/apps/we/nioc.vp?cid=10026〈=US
Jochen Klier
Application Engineering Group Leader
NI-Germany