I think I know what you're trying to do.
I had a similar idea to gear two axes to allow me to correct a tilt angle with two linear steppers, but non-linear gearing isn't possible I think.
What is possible however, is generating a vector space based on the two motors involved. Then, in interpreting the two motors as X and Y (Which they aren't, but for the sake of getting the software to do what we want, we have to think like they are), we can make a contoured move in the XY plane. This way, we can effectively couple the movement of the two motors in any way we choose. By altering the contour, we can alter how the two motors run in relation to each other.
A straight-line contour will act like a static gearing ratio, whereas any curved contour will result in a dynamically changing relationship between the two motors (just like dynamically changing gear ratios).
It's a bit twiddly, and to be honest I've never done it myself (I solved my problem in another way) but I'm pretty sure it should work.
Either way, I hope this helps
Shane.
Using LV 6.1 and 8.2.1 on W2k (SP4) and WXP (SP2)