Hi Travis,
I'm assuming that you have attempted to run the shipping example Acq&Graph Voltage-Int Clk-Dig Start.vi. It sounds like this example is most applicable to what you are trying to do. Verify that you have the digital trigger signal connected to the same line that you have configured in LabVIEW. You indicate that you want the acquisition to trigger when the digital signal crosses 0. Does this mean that you are triggering off of a falling edge? If so, make sure that this parameter is correctly wired in your DAQmx Start Trigger (Digital Edge).vi.
From the behavior you are seeing, it seems like your VI is waiting for the digital trigger to occur but it does not. Make sure that your external digital signal is giving you a falling edge that you can use as a trigger.
Regards,
Andrew W
National Instruments