Hi Gabs,
the different DAQ series support also different possibillities for synchronization. RTSI is one solution that works over different DAQ cards, but cannot be used for devices which don't support that feature. Maybe you can use a general clock signal for synchronizing the different DAQ cards which is created by an counter output of one card, therefore you have to use external connections instead of a RTSI cable.
See also the following KB link to that: http://forums.ni.com/ni/board/message?board.id=250&message.id=25329
For a general application you have to implement all possibillities of your synchronisation mechanisms. For most of them are example VI's available in the LabVIEW example library.
The NI Developer Zone describes also many synchronization mechanisms, here are some importent links that might be helpful:
http://zone.ni.com/devzone/cda/tut/p/id/4322
http://zone.ni.com/devzone/cda/tut/p/id/3615
regards,
Nikolai