Rajat,
If you are multiplexing all of the SCXI modules, then only analog input channel 0 of the PXI-6025E is being used by SCXI. Therefore, you can use all other analog input channels for acquiring other signals.
To access those channels in software, you will just point to a channel on the PXI-6025 (device 4 in your case). For instance, if you want to test a sensor reading in Measurment and Automation Explorer (MAX), you would right click on the PXI-6025E within devices and interfaces and select test panels and go to any channel other than channel 0. You will basically treat the signals going to the CB50LP as signals going directly to the 6025E and SCXI will have nothing to do with those readings.
Accessing the Unused Analog Input Channels of a DAQ Board Att
ached to an SCXI Chassis in Multiplexed Mode
http://digital.ni.com/public.nsf/websearch/1E9C90A0340B82E4862569520074EB69?OpenDocument