Hello Hilary. The PXI backplane actually has a 10 MHz PXI Clock built into it. The 80 MHz internal timebase of many of our DAQ cards is too fast to pass through the backplane/ RTSI bus. There is a great knowledge base article that explains this in great detail at:
Multi-Device Synchronization
The examples embedded in this article use the DAQmx timing property nodes as well so this should be a great resource for you! Finally, at the very bottom of this page, there is a zip file available for download that contains numerous examples (both PCI and PXI) that deal with multi-device synchronization. Please explore these to get an idea of what is required to programmatically implement this synchronization. I hope this resource is as valuable to you as it is to me. Let me know if you have any questions about it and I will be happy to address them. Have a great day!
Brian F
Applications Engineer
National Instruments