Pratap,
Thank you for contacting National Instruments!
I will answer your questions in the order I read them

!
No, you will not resolution in your lower scale measurements as long as you specify the range. The DAQmx driver will take the range that you specify and apply its full-scale resolution to that range. Therefore, you could use a range of -1V to 1V, and you will get the full resolution applied to that 2V range.
As long as you have more than one USB port, you can connect more than one device. The NI devices that run over the USB structure are independent of each other, so you should be good to go there!
Yes, the DAQmx software will allow you to choose the window size of your acquisition.
-Jeff P.