Scott,
You don't need to use a digital line to create a TTL pulse. The PCI-6025E has two onboard general purpose counters. You can use one of these counters to create a single pulse of the desired pulse width. For an example of how to program the counters on your board, refer to LabVIEW's Search Examples>>I/O Interfaces>>Counters>>Pulse Generation>>DAQ-STC based.
The advantage of using a counter over the digital line is that it allows you to control the timing of the pulse through hardware and not software. Thus, it is inherently faster, and the timing resolution is more accurate. The counter will count down an internal 20 MHz timebase to create the pulse delay and the pulse width.
For more information on the hardware capabilities of your board, you can refe
r to the User Manual online at www.ni.com/manuals.
Hope this helps.
Regards,
Erin