You can synchronize the clocks of the 5112 by phase locking them together using the same reference clock. If you are using PXI, this can be done by using the 10 MHz backplane clock for both devices. If you are using PCI, you can do this by routing the 10 MHz clock over a RTSI line with a RTSI cable.
Here is an example of synchronizing two 5112 devices. This examples also uses triggering, which will not apply to you, though it will show you how to set the reference clock to be the same.
Brian