I am sorry, but currently NI-Device does not have support for RS-232. It currently only supports GPIB.
The documentation is correct in that IEEE 488.2 is not specific to GPIB and can be implemented on top of other buses. There is a current specification (IEEE 1174) which describes how to implement IEEE 488.2 on top of RS232. If NI adds support for RS-232 in NI-Device, it will likely follow the IEEE 1174 protocol. Being a serial interface, it would only require user-mode pieces.
I will add RS-232 to the list of requested interface buses for future versions of NI-Device. Any information you can provide regarding your desired use would be helpful.
Thanks,
Eric Singer
National Instruments