Santanu:
Are you using INSTR or SOCKET? If INSTR, then there were several bugs fixed in the 2.6 release, specifically regarding large viRead operations. You should consider upgrading.
Also try copying the patches (available from ftp://ftp.ni.com/support/visa/drivers/win32/2.5/patch or ftp://ftp.ni.com/support/visa/drivers/win32/2.6/patch) over the existing NiViEnet.dll on your machine.
If your problems are when using SOCKET, this is not a problem I have heard of before. You may want to use NI Spy and send a capture file to technical support to see if they can help you further.
Dan Mondrik
Senior Software Engineer, NI-VISA
National Instruments