Hey Matt,
I'm a little unsure what you're trying to implement, but I think you should be fine doing what you're requesting at the bottom. You can either manipulate the array once it's within labVIEW, or you should be able to send specific commands to the GPIB instrument. I'm unsure if you've had a chance to use this example, but if you open up labVIEW and go to Help->Find Examples->Search for "GPIB" and you should be able to find "LabVIEW<->GPIB.vi"
This is a great VI, and you can beging sending signals to your instrument with this example. The one thing I can recommend is to find a list of all the commands the instrument is capable of, that information would be found inside the user manual of the instrument. Usually what you can do on the front panel of the instrument, you can do using a modified version of the example.
Can you let me know if this helps?
Regards,
Nick D.