I'm not sure I see where your difficulty is.
I have always used custom scaling, MAX never did quite enough.
I have a cluster for each channel. The cluster contains a scaler (EU/Volt), an offset (EU@0V) and a channel type enum, among other stuff (channel name, units, filters, etc.)
When processing the data, look at the cluster for that channel. Use a CASE statement on the CHANNEL TYPE value. If linear, multiply the volts by the scaler and add the offset - you get EU (Engineering Units) out. If the channel type specifies some other type, use the appropriate linearization routine.
How innacurate would my readings be to use the Labview's Thermocouple scaler VI and set the CJC to 1.25 volts (25 degC) rather than reading from Channel X+8.
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Depends on which type TC, and where you are on it's range. You might expect 20 degrees or more error at the high end of some ranges, without proper CJC.
There's no easy answer to that question.