Hi Azmat,
I simply opened the shipping example "Write Table to XL.vi" and replace the value of "2" in the table with "2000000000000000000000000000000000000000000" and ran the example. It opened up Excel and place "2E+42" in the corresponding cell, so it appears to have worked okay. I'm using LabVIEW 6.1 and Excel 2002.
This, of course, is a floating point number, so it doesn't actually contain that many significant digits. I was not able to create a true 64bit integer value on my computer whether it was in LabVIEW or Excel (which is what I would have expected).
Take a look at the example, and if you have any questions or want to clarify what you are seeing, I'll take a second look at it.
Thanks,