Assuming that you're using DAQmx, all you have to do is specify multiple channels for the DAQmx Create Channel function. For reading channels 0 and 1, use Dev1/ai0:1. For channels 0 through 4, use Dev1/ai0:4. If your board is really a 6034 (there is no 60134), you don't have true simultaneous sampling. There is a single A/D and all of the individual channels are multiplexed or switched to the A/D in the scan order you specify.