Remember that a contour move can represent any kind of profile, including a linear move, so it seems that the easiest way to achieve what you want (i.e. guarantee that you approach (x0,y0) at a specific velocity), is to perform a contour move throughout your application. Alternatively, you could change to velocity mode prior to the contour move to guarantee that you approach (x0,y0) at your desired speed. Finally, you can also do exactly as you said - call the "Start Motion" VI, which will overwrite any previous move.
Also, you are correct in that blending your linear and contour move together will not guarantee that your system moves through point (x0, y0).
I hope this helps! Best wishes with your application!
Best regards,
Dawna P.
Applications Engineer
National Instruments