Hello;
In case the analog input channels are not connected to a valid signal source, that means they are floating. That will make the ADC inputs to float to, since the ADC doesn't know that is not a "valid" data source, the analog to digital convertion will happen on whatever voltage signal is inthe input. That's why you see a voltage even though you don't have a valid source connected to the board.
In case you don't want that to happen, you will need to ground the AI channels, then you will see zero volts.
Hope this helps.
Filipe A.
Applications Engineer
National Instruments