I would assume that your problem is that you're polling each sample individually in software from a fairly high level VI, and LabView probably can't loop much faster than a couple kHz. To get the full 100 kHz in LabView, you'll have to collect batches of samples, like with the N-sample acquisition VIs.
The VI you mention is presumably part of Advantech's proprietary software package that comes with the card, so you should consult their CD-ROM for examples. I've never used Advantech, but I've bought DAQ cards from 3 or 4 different vendors, and they always have examples for this.